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The percentage calculation of crystalline phases in atmospheric particulate matter samples by means of an adiabatic approach of the matrix-flushing method with preferred preparations that avoids preferential orientations, should never be interpreted as absolute values. On the contrary, it should be seen as an indicator of the significant differences between each and every analyzed sample. Factors such as the application of constants, which are only useful for preparations of polycrystalline samples free of preferential orientation, and/or like the deficient resolution shown by the diffraction diagrams for certain phyllosilicate phases, bring a high degree of uncertainty to these percentage calculations. An alternative method of crystalline and amorphous phase quantification is presented below. Once the majority phases in the samples were identified, appropriate pure phases corresponding to each of them were selected. Then, the corresponding calibration curves were built using corundum (number 676 NIST) as a reference pattern phase. After validating the obtained calibration curves, the constants corresponding to each phase and selected spacing were calculated. The ALJOR method has been used for the quantification of five samples.  相似文献   
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This article describes various statistical analyses of plume-length data to evaluate the hypothesis that the presence of ethanol in gasoline may hinder the natural attenuation of hydrocarbon releases. Plume dimensions were determined for gasoline-contaminated sites to evaluate the effect of ethanol on benzene and toluene plume lengths. Data from 217 sites in Iowa (without ethanol; set 1) were compared to data from 29 sites in Kansas that were contaminated by ethanol-amended gasoline (10% ethanol by volume; set 2). The data were log-normally distributed, with mean benzene plume lengths (± standard deviation) of 193 ± 135 feet for set 1 and 263 ± 103 feet for set 2 (36% longer). The median lengths were 156 feet and 263 feet (69% longer), respectively. Mean toluene plume lengths were 185± 131 feet for set 1 and 211 ±99 feet for set 2 (14% longer), and the median lengths were 158 feet and 219 feet (39% longer), respectively. Thus, ethanol-containing BTEX plumes were significantly longer for benzene (p < 0.05), but not for toluene. A Wilcoxon signed rank test showed that toluene plumes were generally shorter than benzene plumes, which suggests that toluene was attenuated to a greater extent than benzene. This trend was more pronounced for set 2 (with ethanol), which may reflect that benzene attenuation is more sensitive to the depletion of electron acceptors caused by ethanol degradation. These results support the hypothesis that the presence of ethanol in gasoline can lead to longer benzene plumes. The importance of this effect, however, is probably site-specific, largely depending on the release scenario and the available electron acceptor pool.  相似文献   
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The age and tectonosedimentary environment of the Palaeozoic sediments on the Frontal Cordillera is not well known and earlier studies have been unable to satisfactorily explain the geological history of the basement of the Andes.In the vicinity of the old Castaño Viejo mine crop out various levels of partially metamorphosed microbialite limestones, which alternate with thin marly–lutitic interstrata. These levels contain abundant palynomorph remains, which allow the series to be dated as Silurian–Devonian. These data, together with the presence of warm climate fossils, lend support to the hypothesis of a major allochtony of the Chilenia Terrane (of which the Frontal Cordillera formed part), relative to the Cuyania Terrane (which included the Precordillera), prior to their amalgamation.Upper Carboniferous palynomorphs found during this study occur in association with resedimented palynomorphs and chitinozoa, of possible Devonian age. This demonstrates the equivalence of both fossiliferous series and their location within the upper part of the Upper Carboniferous Agua Negra Fm. The Silurian–Devonian elements, deformed during a phase prior to the Gondwanic orogeny, were eroded and transported to the foreland basin during the Upper Carboniferous.The palynomorph associations found in all samples correspond to the Ancistrospora palynological zone and to the Raistrickia densaConvolutispora muriornata Biozone, which are indicative of Upper Carboniferous times. Characteristic forms such as Ancistrospora verrucosa and C. muriornata, both indicative of an Upper Carboniferous age, were found in samples from the Castaño Viejo area.Earlier interpretations of the Frontal Cordillera attributing the sedimentation to a palaeo-latitude at some distance from Gondwana, were based on the presence of Silurian–Devonian hot water stromatolithic limestones. Our results suggest that Cuyania and Chilenia were not necessarily separated by a great distance before their amalgamation. This in turn means that a large ocean was not necessarily consumed in the process.  相似文献   
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The regional influence of the Madden–Julian oscillation (MJO) on South America is described. Maps of probability of weekly-averaged rainfall exceeding the upper tercile were computed for all seasons and related statistically with the phase of the MJO as characterized by the Wheeler–Hendon real-time multivariate MJO (RMM) index and with the OLR MJO Index. The accompanying surface air temperature and circulation anomalies were also calculated. The influence of the MJO on regional scales along with their marked seasonal variations was documented. During December–February when the South American monsoon system is active, chances of enhanced rainfall are observed in southeastern South America (SESA) region mainly during RMM phases 3 and 4, accompanied by cold anomalies in the extratropics, while enhanced rainfall in the South Atlantic Convergence Zone (SACZ) region is observed in phases 8 and 1. The SESA (SACZ) signal is characterized by upper-level convergence (divergence) over tropical South America and a cyclonic (anticyclonic) anomaly near the southern tip of the continent. Impacts during March–May are similar, but attenuated in the extratropics. Conversely, in June–November, reduced rainfall and cold anomalies are observed near the coast of the SACZ region during phases 4 and 5, favored by upper-level convergence over tropical South America and an anticyclonic anomaly over southern South America. In September–November, enhanced rainfall and upper-level divergence are observed in the SACZ region during phases 7 and 8. These signals are generated primarily through the propagation of Rossby wave energy generated in the region of anomalous heating associated with the MJO.  相似文献   
7.
The long-term variability of rainfall in the Soummam watershed (NE Algeria) has been analysed over the past 108 years using continuous wavelet method in order to identify the interannual modes controlling the rainfall variability. Statistical analyses of rainfall timeseries have shown its distribution following five periods of time, limited by a series of discontinuities around 1935, 1950, 1970 and 1990. The continuous wavelet transform have demonstrated different low frequency modes: 2–4, 4–8, 8–16 and 16–32 years.The annual band is expanded during the full study period with some pics around 1905, 1920–1935 and 1960; it shows a negative long-term trend, in particular since the period 1970–1990 when a major change has been identified. Then, the relationships between climate patterns of North Atlantic Oscillation (NAO) and Southern Oscillation Index (SOI) and the hydrological variability in the frequency domain have been investigated; they have shown a mean explained variance of 40 and 24 %, respectively. Such variances are less obvious for the annual mode and increase for the interannual frequencies. The coherence suffer from high perturbations since the period 1970–1990 when the NAO (SOI) shifts from negative (positive) phases to positive (negative) ones. Such anomalies are responsible for significant changes of rainfall variability, emphasising the global warming effects.  相似文献   
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Natural Hazards - Flooding is the most costly type of natural disaster, as well as the most frequent. To provide risk-based flood insurance, providers must be able to accurately determine an...  相似文献   
9.
Thermohaline variables were simultaneously measured, July 17, 2000, at four Galician rias under favourable upwelling conditions to analyse upwelling intensity. The intensity of coastal upwelling is shown to be strongly dependent on the wind pattern. The maximum amplitudes of wind stress were observed at the western coast (0.30 Nm-2) with southward direction (favourable to upwelling) and these are shown to be related to low temperature (12°C) and high salinity (35.8) in the estuaries mouth. From Cape Finisterre to Cape Estaca de Bares the wind stress showed a lower magnitude (0.05-0.10 Nm-2) with a direction oblique to the coast. The temperature showed an increase (14°C) and the salinity a decrease (35.4) because the lower upwelling intensity at this part of the coast. The observed decrease in upwelling from south to north is not an isolated event, since the measured wind conditions are persistent during summer months, at least in the period with available QuikSCAT data (1999-2004).  相似文献   
10.
An overview of the crust and upper mantle structure of Central America and the Caribbean region is presented as a result of the processing of more than 200 seismograms recorded by digital broadband stations from SSSN and GSN seismic networks. Group velocity dispersion curves are obtained in the period range from 10s to 40s by FTAN analysis of the fundamental mode of the Rayleigh waves; the error of these measurements varies from 0.06 and 0.09 km/s. From the dispersion curve, seven tomographic maps at different periods and with average spatial resolution of 500 km are obtained. Using the logical combinatorial classification techniques, eight main groups of dispersion curves are determined from the tomographic maps and eleven main regions, each one characterized by one kind of dispersion curves, are identified. The average dispersion curves obtained for each region are extended to 150s by adding data from a larger-scale tomographic study (Vdovin et al., 1999) and inverted using a nonlinear procedure. A set of models of the S-wave velocity vs. depth in the crust and upper mantle is found as a result of the inversion process. In six regions we identify a typically oceanic crust and upper mantle structure, while in the other two the models are consistent with the presence of a continental structure. Two regions, located over the major geological zones of the accretionary crust of the Caribbean region, are characterized by a peculiar crust and upper mantle structure, indicating the presence of lithospheric roots reaching, at least, about 200 km of depth.  相似文献   
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